Browsing by Author "Zeh, Armin"

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    Alabandite (MnS) in metamorphosed manganiferous rocks at Morro da Mina, Brazil : palaeoenvironmental significance.
    (2019) Cabral, Alexandre Raphael; Zeh, Armin; Viana, Nívea Cristina da Silva; Castro, Marco Paulo de; František, Lehmann; Queiroga, Gláucia Nascimento
    The mineral alabandite, cubic MnS with variable amounts of FeS, occurs in a number of mineral assemblages in manganiferous metasedimentary rocks, some of which are mined as manganese ore. One of them is Morro da Mina, Mina Gerais, Brazil, where alabandite is a minor component of “queluzite”, a manganese-silicate–carbonate rock. The Morro da Mina alabandite contains 7.3 ± 1.4 mol% FeS and makes up aggregates with graphite and molybdenite. A comparison of alabandite occurrences worldwide indicates four main types of mineral assemblages: (1) alabandite + graphite; (2) alabandite + graphite + molybdenite; (3) alabandite + rhodochrosite + molybdenite; (4) and alabandite + rhodochrosite. The different assemblages suggest that manganese sulfide formed in a range of marine palaeoenvironments, from highly reducing and sulfidic – i.e., euxinic – settings to manganeseoxide-precipitating conditions. Morro da Mina represents assemblage (2), which is characteristic of a euxinic water column in a stratified ocean. In general, our comparison of alabandite-bearing mineral assemblages indicates that palaeoenvironmental information can be retrieved from sedimentary rocks that experienced variable degrees of metamorphic overprint.
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    Zircon geochronology and Hf isotopes of the Dwalile Supracrustal Suite, Ancient Gneiss Complex, Swaziland : insights into the diversity of Palaeoarchaean source rocks, depositional and metamorphic ages.
    (2017) Schijndel, Valby van; Stevens, Gary; Zeh, Armin; Lana, Cristiano de Carvalho
    We report the results of combined U-Pb and Lu-Hf isotope analyses of detrital and metamorphic zircon grains from a variety of metavolcano-sedimentary rocks of the Dwalile Supracrustal Suite (DSS) from the ca. 3.66 to 3.20 Ga Ancient Gneiss Complex (AGC) in Swaziland. The results indicate that the DSS is made up by Palaeo- and Mesoarchaean rocks which have been affected by a polymetamorphic overprint and became tectonically assembled during the Neoarchaean. The oldest Dwalile rocks were formed during a phase of felsic to intermediate volcanism at ca. 3.46 Ga, and are derived from the same magma source as the Tsawela Gneisses. Based on the combined U-Pb-Hf isotope data, two groups of metasedimentary rocks can be distinguished: an older Dwalile Group I that is similar in age to the Hooggenoeg and Kromberg Formations (3.46–3.40 Ga), but with a different source area. A younger Dwalile Group II is coeval with the Fig Tree and possibly Moodies Groups (<3.23 Ga) and the data suggest there was a similar provenance. The U-Pb-Hf isotope data and petrological observations demonstrate that the DSS was affected by three stages of metamorphic overprint: an event at 3.23 Ga, pervasive amphibolite-facies metamorphism at 3.15 Ga, and low-P granulite-facies metamorphism at 2.99 Ga. Metamorphic zircon in the amphibolitefacies rocks resulted from new growth in aqueous fluids at 3.15 Ga, whereas in the granulite-facies rocks new zircon was formed in the presence of melt. The 3.23 Ga event coincides with the last significant metamorphic overprint documented in the Barberton Greenstone Belt (BGB), whereas as two younger events are restricted to the AGC. The data support the model suggesting amalgamation between the AGC and BGB terranes at ca. 3.23 Ga. In addition, they require crustal thickening in the AGC terrane at ca. 3.15 Ga, causing Barrovian-type metamorphism in the DSS and granulite-facies metamorphism in the Luboya-Kubuta Terrane. Low-P granulite-facies metamorphism at ca. 2.99 Ga is most likely related to crustal extension during the onset of Pongola Basin rifting, causing mantle upwelling, mafic magmatism, and heat transfer from the mantle into the thinned crust.