Synthesis of 2,1,3-Benzoxadiazole derivatives as new fluorophores-combined experimental, optical, electro, and theoretical study.

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dc.contributor.authorFrizon, Tiago Elias Allievi
dc.contributor.authorVieira, André Alexandre
dc.contributor.authorSilva, Fabrícia Nunes da
dc.contributor.authorSaba, Sumbal
dc.contributor.authorFarias, Giliandro
dc.contributor.authorSouza, Bernardo de
dc.contributor.authorZapp, Eduardo
dc.contributor.authorLôpo, Michell N.
dc.contributor.authorBraga, Hugo de Campos
dc.contributor.authorGrillo, Felipe Fardin
dc.contributor.authorCurcio, Sergio Fernando
dc.contributor.authorCazati, Thiago
dc.contributor.authorRafique, Jamal
dc.date.accessioned2022-03-16T18:11:31Z
dc.date.available2022-03-16T18:11:31Z
dc.date.issued2020pt_BR
dc.description.abstractHerein, we report the synthesis and characterization of fluorophores containing a 2,1,3-benzoxadiazole unit associated with a π-conjugated system (D-π-A-π-D). These new fluorophores in solution exhibited an absorption maximum at around ∼419 nm (visible region), as expected for electronic transitions of the π-π ∗ type (ε ∼2.7 × 107 L mol−1 cm−1 ), and strong solvent-dependent fluorescence emission (ΦFL ∼0.5) located in the bluish-green region. The Stokes’ shift of these compounds is ca. 3,779 cm−1 , which was attributed to an intramolecular charge transfer (ICT) state. In CHCl3 solution, the compounds exhibited longer and shorter lifetimes, which was attributed to the emission of monomeric and aggregated molecules, respectively. Density functional theory was used to model the electronic structure of the compounds 9a–d in their excited and ground electronic states. The simulated emission spectra are consistent with the experimental results, with different solvents leading to a shift in the emission peak and the attribution of a π-π ∗ state with the characteristics of a charge transfer excitation. The thermal properties were analyzed by thermogravimetric analysis, and a high maximum degradation rate occurred at around 300◦C. Electrochemical studies were also performed in order to determine the band gaps of the molecules. The electrochemical band gaps (2.48–2.70 eV) showed strong correlations with the optical band gaps (2.64–2.67 eV).pt_BR
dc.identifier.citationFRIZON, T. E. A. et al. Synthesis of 2,1,3-Benzoxadiazole derivatives as new fluorophores-combined experimental, optical, electro, and theoretical study. Frontiers in Chemistry, v. 8, maio 2020. Disponível em: <https://www.frontiersin.org/articles/10.3389/fchem.2020.00360/full>. Acesso em: 25 ago. 2021.pt_BR
dc.identifier.doihttps://doi.org/10.3389/fchem.2020.00360pt_BR
dc.identifier.issn2296-2646
dc.identifier.urihttp://www.repositorio.ufop.br/jspui/handle/123456789/14682
dc.language.isoen_USpt_BR
dc.rightsabertopt_BR
dc.rights.licenseThis is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. Fonte: o PDF do artigo.pt_BR
dc.subjectHeterocyclespt_BR
dc.subjectLuminescencept_BR
dc.subjectTetrazolept_BR
dc.titleSynthesis of 2,1,3-Benzoxadiazole derivatives as new fluorophores-combined experimental, optical, electro, and theoretical study.pt_BR
dc.typeArtigo publicado em periodicopt_BR
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