Determination of rare earth elements in Fe-minerals using external calibration by LA-ICP-MS and application on Cauê Iron Formation (Brazil).

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dc.contributor.authorSousa, Denise Versiane Monteiro de
dc.contributor.authorAbreu, Adriana Trópia de
dc.contributor.authorSampaio, Geraldo Magela Santos
dc.contributor.authorLana, Cristiano de Carvalho
dc.contributor.authorRodrigues, Daniel Aparecido da Silva
dc.contributor.authorNalini Júnior, Hermínio Arias
dc.date.accessioned2021-07-27T15:10:50Z
dc.date.available2021-07-27T15:10:50Z
dc.date.issued2020pt_BR
dc.description.abstractThe rare earth elements (REE) composition in Fe-mineral phases is an important tool in iron formation studies to obtain information about parent rocks and environmental and paragenetic processes. However, the determination of REE presents some difficulties, such as the low concentration of these elements, matrix complexity and lack of iron matrix certified reference materials. The aim of the present work is to propose an analytical method to determine the REE plus Y (REE + Y) contents at trace levels in Fe-(hydr)oxides by the laser ablation ICPquadrupoleMS technique, using external calibration. The calibration curves were obtained from analyses of reference materials with different matrices, and the analytical conditions were checked on the NIST 614 glass. The linearity (R2 ≥ 0.98), limit of detection (0.002–0.044 μg g−1), limit of quantification (0.008–0.146 μg g−1), recovery (88.4–112.4%), and intraday (0.1–14.1%) and interday (1.6–17.8%) precision were systematically assessed. The results obtained showed that the method is fit for the purpose and showed evidence of a nonsignificant interference of the matrix. Thus, the developed procedure was applied in the analyses of magnetite, martite, hematite, and goethite grains from Cauê Iron Formation (Brazil). The REE + Y patterns of the minerals are consistent with the previous study of bulk analyses on whole rocks and highlight the postdepositional signature of these elements in banded iron formations.pt_BR
dc.identifier.citationSOUSA, D. V. M. de. et al. Determination of rare earth elements in Fe-minerals using external calibration by LA-ICP-MS and application on Cauê Iron Formation (Brazil). Talanta, v. 219, p. 121239, 2020. Disponível em: <https://www.sciencedirect.com/science/article/abs/pii/S0039914020305300>. Acesso em: 19 fev. 2021.pt_BR
dc.identifier.doihttps://doi.org/10.1016/j.talanta.2020.121239pt_BR
dc.identifier.issn0039-9140
dc.identifier.urihttp://www.repositorio.ufop.br/jspui/handle/123456789/13419
dc.identifier.uri2https://www.sciencedirect.com/science/article/abs/pii/S0039914020305300pt_BR
dc.language.isoen_USpt_BR
dc.rightsrestritopt_BR
dc.subjectREE+Ypt_BR
dc.subjectFe-(hydr)oxidespt_BR
dc.subjectBanded iron formationspt_BR
dc.titleDetermination of rare earth elements in Fe-minerals using external calibration by LA-ICP-MS and application on Cauê Iron Formation (Brazil).pt_BR
dc.typeArtigo publicado em periodicopt_BR
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